
Atomic Structure – Key Points
- Aufbau Principle: Electrons fill sub-levels in order of increasing energy: 1s → 2s → 2p → 3s, etc.
- Azimuthal Quantum Number: Defines the shape of an orbital (s, p, d, f).
- Balmer Series: Lines in the visible region formed when an electron jumps to the 2nd orbit.
- Bracket Series: Lines in the infrared region when electrons jump to the 4th orbit.
- Cathode Rays: Negatively charged particles emitted from the cathode in low-pressure gas.
- Discharge Tube: A tube with low-pressure gas and electrodes for electric current to pass through.
- Heisenberg’s Uncertainty Principle: It’s impossible to know both position and momentum of an electron simultaneously.
- Hund’s Rule: Electrons occupy separate degenerate orbitals with the same spin before pairing.
- Lyman Series: Ultraviolet lines when electrons fall to the 1st orbit.
- Magnetic Quantum Number: Describes the orientation of an orbital in a magnetic field.
- Orbit: A fixed path around the nucleus where an electron revolves.
- Orbital: A region of high probability where an electron can be found.
- Paschen Series: Infrared lines formed when electrons jump to the 3rd orbit.
- Pauli’s Exclusion Principle: No two electrons in the same orbital can have the same four quantum numbers.
- Pfund Series: Infrared lines from transitions to the 5th orbit.
- Positive (Canal) Rays: Positively charged rays traveling opposite to cathode rays in a discharge tube.
- Principal Quantum Number: Represents the main energy level or shell (symbol: n).
- Quantum Numbers: A set of four numbers that describe an electron’s position and behavior.
- Sigma Bond: A bond formed by the head-on overlap of orbitals.
- Spectrum: A band of colors formed when white light is dispersed through a prism.
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